Armarouge is not found in the wild. Catch Charcadet on Steam Chamber or Appendix:Brick Bronze Walkthrough/Extra 3, then an Auspicious Armor turns it into Armarouge.
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Speed at level 100: slowest with 0 IV, 0 EVs and a −Speed nature; fastest with 31 IV, 252 EVs and a +Speed nature.